| Athletic | 21:00 - 01/12/2013 | Barcelona | |
| Betis | 12:00 - 01/12/2013 | Rayo | |
| Celta | 3-1 | Almería | |
| Espanyol | 1-2 | R. Sociedad | |
| R. Madrid | 4-0 | Valladolid | |
| Valencia | 19:00 - 01/12/2013 | Osasuna | |
| Villarreal | 1-1 | Málaga | |
| Elche | 0-2 | Atlético | |
| Getafe | 1-0 | Levante | |
| Granada | 17:00 - 01/12/2013 | Sevilla |